Four things that can happen to a photon
Light inside a participating medium
A surface gives a ray one decision, at one point. A medium interrogates it continuously: everywhere along its path the light can be swallowed, knocked off course, joined by light arriving from elsewhere, or added to by the medium glowing on its own. Switch the four mechanisms on and off and watch both the photons and the radiance curve respond.
Two terms add radiance and two remove it. Everything else in this chapter is bookkeeping on top of this one line.
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Turn off absorption but leave out‑scattering on, then do the reverse. The photon counters tell two completely different stories — but the radiance curve, and therefore the eye, cannot tell them apart. That indistinguishability is why the two coefficients get merged into a single extinction coefficient on the next page.